In case anyone comes across this thread, like I did, I had this issue trying to run my app on a Mac M1 (arm64) on an iOS simulator. Because Qt's iOS simulator kits only support x86_64, it builds for the 'Rosetta' simulators. As far as I'm aware, this has been the case since Qt started supporting Apple Silicon.
The important piece of info is that there was a mistake in some of the Qt 6.8 builds - they included arm64 ffmpeg libraries for iOS simulator whereas they should have included x86_64 ones. This affects Qt 6.8.3 and possibly earlier versions. It was fixed in Qt 6.8.4.
I encountered the exact same errors and warnings as the OP, using Qt 6.8.3. The problem disappeared by switching to Qt 6.8.4.