If you are not interested to high performance Python is definitely simpler to learn; but this also depends to your experience (which languages do you know?).
But, keep in mind that, as I said before, the official language for Qt in C++ and Python are available only using 3rdparty libraries.
For the database could be interesting know if you want use a standard relational DB (SQLite, MySQL, PostgreSQL, ORALCE, ....) or something else (MongoDB, noSQL, ....). In the first case Qt offers opportunity to write write code independent of the DB using QtSql drivers; in the second case you have to use a 3rdparty library.
If you need to have your application ready as soon as possible I suggest Python but if you want to learn Qt go to C++
Bye